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Decode Chemistry for JNTU-H 18 Course (I - I - EEE/CSE/IT - CH102BS)

SKU: 9789333218924
M. A. Jail, A. P. Kulkarni ISBN-9789333218924 Buy Kindle Edition Buy Printed Book
₹ 150.00
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Unit - I : Molecular Structure and Theories of Bonding
Atomic and Molecular orbitals. Linear Combination of Atomic Orbitals (LCAO), molecular orbitals of diatomic molecules, molecular orbital energy level diagrams of , and molecules. molecular orbitals of butadiene and benzene. Crystal Field Theory (CFT): Salient Features of CFT - Crystal Field Splitting of transition metal ion d-orbitals in Tetrahedral, Octahedral and square planar geometries. Band structure of solids and effect of doping on conductance. (Chapter - 1)
Unit - II : Water and its Treatment
Introduction - hardness of water - Causes of hardness - Types of hardness: temporary and permanent - expression and units of hardness - Estimation of hardness of water by complexometric method. Potable water and its specifications. Steps involved in treatment of water - Disinfection of water by chlorination and ozonization. Boiler feed water and its treatment - Calgon conditioning, Phosphate conditioning and Colloidal conditioning. External treatment of water - Ion exchange process. Desalination of water - Reverse osmosis. Numerical problems. (Chapter - 2)
Unit - III : Electrochemistry and Corrosion
Electrochemical cells - electrode potential, standard electrode potential, types of electrodes - calomel, Quinhydrone and glass electrode. Nernst equation, Determination of pH of a solution by using quinhydrone and glass electrode. Electrochemical series and its applications. Numerical problems. Potentiometric titrations. Batteries - Primary (Lithium cell) and secondary batteries (Lead - acid storage battery and Lithium ion battery). Causes and effects of corrosion - theories of chemical and electrochemical corrosion - mechanism of electrochemical corrosion, Types of corrosion: Galvanic, water-line and pitting corrosion. Factors affecting rate of corrosion, Corrosion control methods- Cathodic protection - Sacrificial anode and impressed current cathodic methods. Surface coatings - metallic coatings - methods of application. Electroless plating of Nickel. (Chapter - 3)
Unit - IV : Stereochemistry, Reaction Mechanism and Synthesis of Drug Molecules
Introduction to representation of 3-dimensional structures, Structural and stereoisomers, configurations, symmetry and chirality. Enantiomers, diastereomers, optical activity and Absolute configuration. Conformation alanalysis of n- butane. Substitution reactions : Nucleophilic substitution reactions: Mechanism of , reactions. Electrophilic and nucleophilic addition reactions: Addition of HBr to propene. Markownikoff and anti Markownikoff’s additions. Grignard additions on carbonyl compounds. Elimination reactions: Dehydro halogenation of alkylhalides. Saytzeff rule. Oxidation reactions: Oxidation of alcohols using KMn and chromic acid. Reduction reactions: reduction of carbonyl compounds using LiAl & NaB. Hydroboration of olefins. Structure, synthesis and pharmaceutical applications of Paracetamol and Aspirin. (Chapter - 4)
Unit - V : Spectroscopic Techniques and Applications
Principles of spectroscopy, selection rules and applications of electronic spectroscopy. vibrational and rotational spectroscopy. Basic concepts of Nuclear magnetic resonance Spectroscopy, chemical shift. Introduction to Magnetic resonance imaging. (Chapter - 5)

 

Unit - I : Molecular Structure and Theories of Bonding
Atomic and Molecular orbitals. Linear Combination of Atomic Orbitals (LCAO), molecular orbitals of diatomic molecules, molecular orbital energy level diagrams of , and molecules. molecular orbitals of butadiene and benzene. Crystal Field Theory (CFT): Salient Features of CFT - Crystal Field Splitting of transition metal ion d-orbitals in Tetrahedral, Octahedral and square planar geometries. Band structure of solids and effect of doping on conductance. (Chapter - 1)
Unit - II : Water and its Treatment
Introduction - hardness of water - Causes of hardness - Types of hardness: temporary and permanent - expression and units of hardness - Estimation of hardness of water by complexometric method. Potable water and its specifications. Steps involved in treatment of water - Disinfection of water by chlorination and ozonization. Boiler feed water and its treatment - Calgon conditioning, Phosphate conditioning and Colloidal conditioning. External treatment of water - Ion exchange process. Desalination of water - Reverse osmosis. Numerical problems. (Chapter - 2)
Unit - III : Electrochemistry and Corrosion
Electrochemical cells - electrode potential, standard electrode potential, types of electrodes - calomel, Quinhydrone and glass electrode. Nernst equation, Determination of pH of a solution by using quinhydrone and glass electrode. Electrochemical series and its applications. Numerical problems. Potentiometric titrations. Batteries - Primary (Lithium cell) and secondary batteries (Lead - acid storage battery and Lithium ion battery). Causes and effects of corrosion - theories of chemical and electrochemical corrosion - mechanism of electrochemical corrosion, Types of corrosion: Galvanic, water-line and pitting corrosion. Factors affecting rate of corrosion, Corrosion control methods- Cathodic protection - Sacrificial anode and impressed current cathodic methods. Surface coatings - metallic coatings - methods of application. Electroless plating of Nickel. (Chapter - 3)
Unit - IV : Stereochemistry, Reaction Mechanism and Synthesis of Drug Molecules
Introduction to representation of 3-dimensional structures, Structural and stereoisomers, configurations, symmetry and chirality. Enantiomers, diastereomers, optical activity and Absolute configuration. Conformation alanalysis of n- butane. Substitution reactions : Nucleophilic substitution reactions: Mechanism of , reactions. Electrophilic and nucleophilic addition reactions: Addition of HBr to propene. Markownikoff and anti Markownikoff’s additions. Grignard additions on carbonyl compounds. Elimination reactions: Dehydro halogenation of alkylhalides. Saytzeff rule. Oxidation reactions: Oxidation of alcohols using KMn and chromic acid. Reduction reactions: reduction of carbonyl compounds using LiAl & NaB. Hydroboration of olefins. Structure, synthesis and pharmaceutical applications of Paracetamol and Aspirin. (Chapter - 4)
Unit - V : Spectroscopic Techniques and Applications
Principles of spectroscopy, selection rules and applications of electronic spectroscopy. vibrational and rotational spectroscopy. Basic concepts of Nuclear magnetic resonance Spectroscopy, chemical shift. Introduction to Magnetic resonance imaging. (Chapter - 5)

 

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